2026-03-15T21:09:23Z https://tokushima-u.repo.nii.ac.jp/oai

oai:tokushima-u.repo.nii.ac.jp:02006133 2025-04-28T05:52:35Z 1713853213384:1713853295607

Aerobic oxidation of alcohols using bismuth bromide as a catalyst 80361509 上野, 雅晴 ウエノ, マサハル Ueno, Masaharu 上野 ウエノ Ueno 雅晴 マサハル Masaharu 50720710 大村, 聡 オオムラ, サトシ Ohmura, Satoshi 大村 オオムラ Ohmura 聡 サトシ Satoshi 10016173 和田, 眞 ワダ, マコト Wada, Makoto 和田 ワダ Wada 眞 マコト Makoto 40219829 三好, 德和 ミヨシ, ノリカズ Miyoshi, Norikazu 三好 ミヨシ Miyoshi 德和 ノリカズ Norikazu open access Bismuth salts Aerobic oxidation Alcohols Green Sustainable Chemistry We developed an environmentally friendly method for aerobic oxidation of alcohols using a commercially available, relatively benign bismuth salt as a catalyst. We found that the catalytic combination of BiBr3 with nitric acid is key for enhancing the reactivity. The reaction proceeds well under air, making the use of pure oxygen unnecessary. Each of the primary or secondary alcohols tested was oxidized to the corresponding aldehydes or ketones using this protocol. Elsevier 2019-01-18 eng journal article AM 349611 https://tokushima-u.repo.nii.ac.jp/records/2006133 https://doi.org/10.1016/j.tetlet.2019.01.034 10.1016/j.tetlet.2019.01.034 00404039 AA00861801 AA11539822 Tetrahedron Letters 60 7 570 573 https://tokushima-u.repo.nii.ac.jp/record/2006133/files/tetlet_60_7_570_preprint.pdf application/pdf 264 KB 2019-01-30 https://tokushima-u.repo.nii.ac.jp/record/2006133/files/tetlet_60_7_570_accepted.pdf application/pdf 245 KB 2021-01-18