{"created":"2024-10-25T10:04:53.071851+00:00","id":2003252,"links":{},"metadata":{"_buckets":{"deposit":"2a122669-af44-4cee-a4ef-650ae65aabaa"},"_deposit":{"created_by":7,"id":"2003252","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2003252"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02003252","sets":["1713853213384:1713853295607"]},"author_link":["67","250","1229"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"580","bibliographicPageStart":"575","bibliographicVolumeNumber":"43","bibliographic_titles":[{"bibliographic_title":"Journal of Chemical Engineering of Japan","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A microreactor was employed for the oxidative dehydrogenation of propane to propylene in order to suppress a deep oxidation of the resultant propylene to CO and CO2. Magnesium ortho-vanadate, doped and undoped with palladium, and calcium hydroxyapatite, were used as catalysts while the reaction temperature was controlled by steady- and unsteady-state conditions. The enhancement of the selectivity to propylene was the most advantageous effect from using the microreactor, and it occurred when calcium hydroxyapatite was used under an unsteady-state. For example, the selectivity to propylene was 0 and 73.0% using a fixed-bed continuous-flow reactor and the microreactor, respectively, under almost identical propane conversion of 3.1 and 3.2%, respectively. The advantageous effect was also achieved, although to a lesser degree, when magnesium ortho-vanadate was used undoped with palladium under both steady- and unsteady-state conditions. However these advantageous effects of the microreactor were not observed with magnesium ortho-vanadate doped with palladium. With regard to the selectivity to propylene, the redox nature of the catalysts seemed to influence the performance of the microreactor.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_rights_15":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"Copyright © 2010 The Society of Chemical Engineers, Japan","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"収録物ID","attribute_value_mlt":[{"subitem_source_identifier":"00219592","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA00709658","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1715043197608":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access"}]},"item_1722929371688":{"attribute_name":"出版社版DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"10.1252/jcej.43.575"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://doi.org/10.1252/jcej.43.575","subitem_relation_type_select":"DOI"}}]},"item_1723180141928":{"attribute_name":"EID","attribute_value_mlt":[{"subitem_identifier_type":"URI","subitem_identifier_uri":"207607"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"杉山, 茂","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"67","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"杉本, 直登","creatorNameLang":"ja"},{"creatorName":"スギモト, ナオト","creatorNameLang":"ja-Kana"},{"creatorName":"Sugimoto, Naoto","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"尾崎, あづさ","creatorNameLang":"ja"},{"creatorName":"オザキ, アズサ","creatorNameLang":"ja-Kana"},{"creatorName":"Ozaki, Adusa","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"古川, 幸美","creatorNameLang":"ja"},{"creatorName":"フルカワ, ユキミ","creatorNameLang":"ja-Kana"},{"creatorName":"Furukawa, Yukimi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"中川, 敬三","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"250","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"外輪, 健一郎","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"1229","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2017-03-25"}],"displaytype":"detail","filename":"LID201703242003.pdf","filesize":[{"value":"298 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tokushima-u.repo.nii.ac.jp/record/2003252/files/LID201703242003.pdf"},"version_id":"1477bc32-ec33-4c8e-a56b-33be52c7740a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Microreactor","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxidative Dehydrogenation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Propane","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Calcium Hydroxyapatites","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Magnesium Vanadates","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Application of a Microreactor in the Oxidative Dehydrogenation of Propane to Propylene on Calcium Hydroxyapatite and Magnesium ortho-Vanadate Doped and Undoped with Palladium","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Application of a Microreactor in the Oxidative Dehydrogenation of Propane to Propylene on Calcium Hydroxyapatite and Magnesium ortho-Vanadate Doped and Undoped with Palladium","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-03-24"},"publish_date":"2017-03-24","publish_status":"0","recid":"2003252","relation_version_is_last":true,"title":["Application of a Microreactor in the Oxidative Dehydrogenation of Propane to Propylene on Calcium Hydroxyapatite and Magnesium ortho-Vanadate Doped and Undoped with Palladium"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2024-10-28T01:34:33.935481+00:00"}