{"created":"2024-10-28T03:06:34.617635+00:00","id":2004317,"links":{},"metadata":{"_buckets":{"deposit":"83e5fd7d-f68d-44e6-8fe6-b44448e6570f"},"_deposit":{"created_by":7,"id":"2004317","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2004317"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02004317","sets":["1713853213384:1713853295607"]},"author_link":["646","57","596","127"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-03-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"1713","bibliographicPageStart":"1706","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"Journal of Polymer Science Part A : Polymer Chemistry","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"2’,4’-p-Vinylbenzylideneriboflavin (2’,4’-PVBRFl) was prepared as a flavin-containing monomer and copolymerized with divinylbenzene and styrene or its p-substituted derivatives such as 4-acetoxystyrene, 4-vinylbenzyl alcohol, and 4-vinylbenzoic acid to give the corresponding non-functionalized and functionalized PS-DVB-supported flavins PS(H)-DVB-Fl, PS(OAc)-DVB-Fl, PS(CH2OH)-DVB-Fl, and PS(COOH)-DVB-Fl, respectively. PS(OH)-DVB-Fl was also prepared by hydrolysis of PS(OAc)-DVB-Fl under basic conditions. These novel flavin-containing insoluble polymers exhibited characteristic fluorescence in solid state, except PS(OH)-DVB-Fl, and different catalytic activities in aerobic reduction of olefins by in-situ generated diimide from hydrazine depending on their pendant functional group. For example, PS(H)-DVB-Fl was found to be particularly effective for neutral hydrophobic substrates, which could be readily recovered by a simple filtration and reused more than 10 times without loss in catalytic activity. On the other hand, PS(OH)-DVB-Fl and PS(COOH)-DVB-Fl proved to be highly active for phenolic substrates known to be less reactive in the reaction with conventional non-supported flavin catalysts.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"© 2017 Wiley Periodicals, Inc.","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"収録物ID","attribute_value_mlt":[{"subitem_source_identifier":"0887624X","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"10990518","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA1068915X","subitem_source_identifier_type":"NCID"},{"subitem_source_identifier":"AA11624127","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1715043197608":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access"}]},"item_1722929371688":{"attribute_name":"出版社版DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"10.1002/pola.28536"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":" https://doi.org/10.1002/pola.28536","subitem_relation_type_select":"DOI"}}]},"item_1723180141928":{"attribute_name":"EID","attribute_value_mlt":[{"subitem_identifier_type":"URI","subitem_identifier_uri":"322985"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"荒川, 幸弘","creatorNameLang":"ja"},{"creatorName":"アラカワ, ユキヒロ","creatorNameLang":"ja-Kana"},{"creatorName":"Arakawa, Yukihiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"荒川","familyNameLang":"ja"},{"familyName":"アラカワ","familyNameLang":"ja-Kana"},{"familyName":"Arakawa","familyNameLang":"en"}],"givenNames":[{"givenName":"幸弘","givenNameLang":"ja"},{"givenName":"ユキヒロ","givenNameLang":"ja-Kana"},{"givenName":"Yukihiro","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"646","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"262616/profile-ja.html","nameIdentifierScheme":"徳島大学 教育研究者総覧","nameIdentifierURI":"http://pub2.db.tokushima-u.ac.jp/ERD/person/262616/profile-ja.html"},{"nameIdentifier":"70709203","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/search/?qm=70709203"}]},{"creatorNames":[{"creatorName":"カワチ, リサ","creatorNameLang":"ja"},{"creatorName":"カワチ, リサ","creatorNameLang":"ja-Kana"},{"creatorName":"Kawachi, Risa","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"手塚, 美彦","creatorNameLang":"ja"},{"creatorName":"テヅカ, ヨシヒコ","creatorNameLang":"ja-Kana"},{"creatorName":"Tezuka, Yoshihiko","creatorNameLang":"en"}],"familyNames":[{"familyName":"手塚","familyNameLang":"ja"},{"familyName":"テヅカ","familyNameLang":"ja-Kana"},{"familyName":"Tezuka","familyNameLang":"en"}],"givenNames":[{"givenName":"美彦","givenNameLang":"ja"},{"givenName":"ヨシヒコ","givenNameLang":"ja-Kana"},{"givenName":"Yoshihiko","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"127","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"80236976","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/search/?qm=80236976"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"南川, 慶二","creatorNameLang":"ja"},{"creatorName":"ミナガワ, ケイジ","creatorNameLang":"ja-Kana"},{"creatorName":"Minagawa, Keiji","creatorNameLang":"en"}],"familyNames":[{"familyName":"南川","familyNameLang":"ja"},{"familyName":"ミナガワ","familyNameLang":"ja-Kana"},{"familyName":"Minagawa","familyNameLang":"en"}],"givenNames":[{"givenName":"慶二","givenNameLang":"ja"},{"givenName":"ケイジ","givenNameLang":"ja-Kana"},{"givenName":"Keiji","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"57","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"10678/profile-ja.html","nameIdentifierScheme":"徳島大学 教育研究者総覧","nameIdentifierURI":"http://pub2.db.tokushima-u.ac.jp/ERD/person/10678/profile-ja.html"},{"nameIdentifier":"70250959","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/search/?qm=70250959"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"今田, 泰嗣","creatorNameLang":"ja"},{"creatorName":"イマダ, ヤスシ","creatorNameLang":"ja-Kana"},{"creatorName":"Imada, Yasushi","creatorNameLang":"en"}],"familyNames":[{"familyName":"今田","familyNameLang":"ja"},{"familyName":"イマダ","familyNameLang":"ja-Kana"},{"familyName":"Imada","familyNameLang":"en"}],"givenNames":[{"givenName":"泰嗣","givenNameLang":"ja"},{"givenName":"ヤスシ","givenNameLang":"ja-Kana"},{"givenName":"Yasushi","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"596","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"251079/profile-ja.html","nameIdentifierScheme":"徳島大学 教育研究者総覧","nameIdentifierURI":"http://pub2.db.tokushima-u.ac.jp/ERD/person/251079/profile-ja.html"},{"nameIdentifier":"60183191","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/search/?qm=60183191"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2018-03-02"}],"displaytype":"detail","filename":"jpsa_55_10_1706.pdf","filesize":[{"value":"1.66 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tokushima-u.repo.nii.ac.jp/record/2004317/files/jpsa_55_10_1706.pdf"},"version_id":"42c9670e-5881-4739-b492-ba0dde0c583c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"heterogeneous polymers","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"catalysis","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"flavin","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"aerobic oxidation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"fluorescence","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of Insoluble Polystyrene-Supported Flavins and Their Catalysis in Aerobic Reducion of Olefins","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of Insoluble Polystyrene-Supported Flavins and Their Catalysis in Aerobic Reducion of Olefins","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-03-02"},"publish_date":"2018-03-02","publish_status":"0","recid":"2004317","relation_version_is_last":true,"title":["Synthesis of Insoluble Polystyrene-Supported Flavins and Their Catalysis in Aerobic Reducion of Olefins"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2025-01-29T03:06:08.706802+00:00"}