{"created":"2024-10-28T03:16:30.264320+00:00","id":2004440,"links":{},"metadata":{"_buckets":{"deposit":"0b657703-93a3-4633-84d3-37be450a0446"},"_deposit":{"created_by":7,"id":"2004440","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2004440"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02004440","sets":["1713853213384:1713853295607"]},"author_link":["355"],"item_10001_alternative_title_1":{"attribute_name":"タイトル別表記","attribute_value_mlt":[{"subitem_alternative_title":"Analysis of Valence for Chromate Conversion Coatings Using Laboratory XAFS Spectrometer and a Comparison with X-ray Photoelectron Spectroscopy","subitem_alternative_title_language":"en"}]},"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-12-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"869","bibliographicPageStart":"864","bibliographicVolumeNumber":"95","bibliographic_titles":[{"bibliographic_title":"鉄と鋼","bibliographic_titleLang":"ja"},{"bibliographic_title":"Tetsu-to-Hagané","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We performed a nondestructive and in laboratory evaluation technique of hexavalent chromium (Cr(VI)) in chromate conversion coatings using a laboratory X-ray absorption fine structure (XAFS) spectrometer equipped with W anode X-ray tube. The recorded XANES spectrum of a chromate conversion coating sample with fluorescence mode possessed the Cr–K X-ray absorption edge. We have obtained calibration curves of the ratio of Cr(VI)/Cr(III) by the height of pre-edge peak and the Cr–K X-ray absorption edge energy of the reference samples prepared by Cr2O3 (Cr(III)) and CrO3 (Cr(VI)) particle reagents. The calibration curves showed the high correlation coefficients such as 1.00 for the height of pre-edge peak and 0.99 for the value of the energy on the Cr–K X-ray absorption edge. The ratio of Cr(VI)/Cr(III) in the chromate conversion coating has also been evaluated by the X-ray photoelectron spectroscopy (XPS) and 1,5-diphenyl-carbazide absorption spectrometry (DPC) methods. The ratio of Cr(VI)/Cr(III) evaluated by the laboratory XAFS spectrometer was almost identical to that by XPS method.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"一般社団法人 日本鉄鋼協会","subitem_publisher_language":"ja"}]},"item_10001_rights_15":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"© 2009 一般社団法人 日本鉄鋼協会","subitem_rights_language":"ja"}]},"item_10001_source_id_9":{"attribute_name":"収録物ID","attribute_value_mlt":[{"subitem_source_identifier":"18832954","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"00211575","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA12060774","subitem_source_identifier_type":"NCID"},{"subitem_source_identifier":"AN00151251","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1715043197608":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access"}]},"item_1722929371688":{"attribute_name":"出版社版DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"10.2355/tetsutohagane.95.864"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.2355/tetsutohagane.95.864","subitem_relation_type_select":"DOI"}}]},"item_1723180141928":{"attribute_name":"EID","attribute_value_mlt":[{"subitem_identifier_type":"URI","subitem_identifier_uri":"207332"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"宮内, 宏哉","creatorNameLang":"ja"},{"creatorName":"ミヤウチ, ヒロヤ","creatorNameLang":"ja-Kana"},{"creatorName":"Miyauchi, Hiroya","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"山本, 孝","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"355","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"北垣, 寛","creatorNameLang":"ja"},{"creatorName":"キタガキ, ヒロシ","creatorNameLang":"ja-Kana"},{"creatorName":"Kitagaki, Hiroshi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"中村, 知彦","creatorNameLang":"ja"},{"creatorName":"ナカムラ, トモヒコ","creatorNameLang":"ja-Kana"},{"creatorName":"Nakamura, Tomohiko","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"中西, 貞博","creatorNameLang":"ja"},{"creatorName":"ナカニシ, サダヒロ","creatorNameLang":"ja-Kana"},{"creatorName":"Nakanishi, Sadahiro","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"河合, 潤","creatorNameLang":"ja"},{"creatorName":"カワイ, ジュン","creatorNameLang":"ja-Kana"},{"creatorName":"Kawai, Jun","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2018-03-22"}],"displaytype":"detail","filename":"tth_95_12_864.pdf","filesize":[{"value":"429 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tokushima-u.repo.nii.ac.jp/record/2004440/files/tth_95_12_864.pdf"},"version_id":"51edc79d-997d-4f9e-8d5e-de8ab4eccacd"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"laboratory XAFS","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"XANES","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"chromate conversion coating","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"hexavalent chromium","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"実験室系X線吸収分光分析装置を用いたクロメート皮膜中クロムの価数評価及びX線光電子スペクトルとの比較検討","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"実験室系X線吸収分光分析装置を用いたクロメート皮膜中クロムの価数評価及びX線光電子スペクトルとの比較検討","subitem_title_language":"ja"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-03-22"},"publish_date":"2018-03-22","publish_status":"0","recid":"2004440","relation_version_is_last":true,"title":["実験室系X線吸収分光分析装置を用いたクロメート皮膜中クロムの価数評価及びX線光電子スペクトルとの比較検討"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2024-10-28T03:16:38.264992+00:00"}