{"created":"2024-10-28T05:59:50.536710+00:00","id":2005041,"links":{},"metadata":{"_buckets":{"deposit":"00c7828e-ac14-41ab-95a2-a6b94989b8e5"},"_deposit":{"created_by":7,"id":"2005041","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2005041"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02005041","sets":["1713853213384:1713853295607"]},"author_link":["720","650"],"item_10001_alternative_title_1":{"attribute_name":"タイトル別表記","attribute_value_mlt":[{"subitem_alternative_title":"Facile Guanidine Formation under Mild Acidic Condition","subitem_alternative_title_language":"en"}]},"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-08-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"18","bibliographicPageEnd":"2596","bibliographicPageStart":"2591","bibliographicVolumeNumber":"27","bibliographic_titles":[{"bibliographic_title":"Synlett","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"An efficient method for converting isothioureas into guanidines was developed. The use of amine salts of bis(trifluoromethanesulfonyl)imide as a nitrogen source was found to induce an efficient conversion under weak acidic condition at 50 °C. The conversion was applicable to the various amines and carbamate-protected thioureas, and various carbamate-protected cyclic guanidines were obtained in high yields. In particular, ammonium bis(trifluoromethanesulfonyl)imide salt is a useful N1 source with which to construct mono-protected cyclic guanidines.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Thieme","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"© 2016 Georg Thieme Verlag Stuttgart · New 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bis(trifluoromethansulfonyl)imidate","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Facile Guanidine Formation under Mild Acidic Conditions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Facile Guanidine Formation under Mild Acidic Conditions","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-29"},"publish_date":"2018-06-29","publish_status":"0","recid":"2005041","relation_version_is_last":true,"title":["Facile Guanidine Formation under Mild Acidic Conditions"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2025-01-28T02:25:23.244271+00:00"}