{"created":"2024-10-30T09:04:18.448752+00:00","id":2007194,"links":{},"metadata":{"_buckets":{"deposit":"45a79c2b-e302-4c53-9a55-816704952026"},"_deposit":{"created_by":7,"id":"2007194","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2007194"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02007194","sets":["1713853213384:1713853295607"]},"author_link":["549","807"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-08-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"946","bibliographicPageStart":"941","bibliographicVolumeNumber":"36","bibliographic_titles":[{"bibliographic_title":"Analytical Sciences","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Water-soluble carbon nanodots (CND) were synthesized under microwave irradiation from glutamic acid or glutamic acid–boric acid mixture. The CNDs were collected in an aqueous solution through size fractionation by centrifugal filtration. The CNDs thus prepared were subjected to characterization by capillary electrophoresis (CE). A peak signal of anionic substance was detected in the electropherogram, and it was found to be a major component of the CNDs. The effective electrophoretic mobility of the major component was almost identical over the pH range between 6.7 and 11.6, suggesting that the functional group of amine or boric acid moiety was not included in the CNDs. The effective electrophoretic mobility decreased at an acidic pH of less than 5, and it was suggested that carboxylate moiety was included in the CNDs. A signal of less-charged CNDs was also detected in the electropherogram, and the CNDs were characterized by a CE format of micellar electrokinetic chromatography. Two or four peaks were detected just after the electroosmotic flow; the less-charged CNDs were thus hydrophilic. The affinity interaction was also examined between the major anionic CNDs and a hydrophobic pairing cation. The peak signal of the major anionic CNDs broadened, and its theoretical number of plates decreased in the presence of tetrabutylammonium ion in the separation buffer. A small portion of the anionic CNDs were a little hydrophobic at different degrees, and their effective electrophoretic mobility decreased by the hydrophobic interaction, resulting in peak broadening of the anionic CNDs.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Society for Analytical Chemistry","subitem_publisher_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"収録物ID","attribute_value_mlt":[{"subitem_source_identifier":"13482246","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"09106340","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA10500785","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1715043197608":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access"}]},"item_1722929371688":{"attribute_name":"出版社版DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"10.2116/analsci.19P484"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.2116/analsci.19P484","subitem_relation_type_select":"DOI"}}]},"item_1723180141928":{"attribute_name":"EID","attribute_value_mlt":[{"subitem_identifier_type":"URI","subitem_identifier_uri":"362803"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"髙栁, 俊夫","creatorNameLang":"ja"},{"creatorName":"タカヤナギ, トシオ","creatorNameLang":"ja-Kana"},{"creatorName":"Takayanagi, Toshio","creatorNameLang":"en"}],"familyNames":[{"familyName":"髙栁","familyNameLang":"ja"},{"familyName":"タカヤナギ","familyNameLang":"ja-Kana"},{"familyName":"Takayanagi","familyNameLang":"en"}],"givenNames":[{"givenName":"俊夫","givenNameLang":"ja"},{"givenName":"トシオ","givenNameLang":"ja-Kana"},{"givenName":"Toshio","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"549","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"241977/profile-ja.html","nameIdentifierScheme":"徳島大学 教育研究者総覧","nameIdentifierURI":"http://pub2.db.tokushima-u.ac.jp/ERD/person/241977/profile-ja.html"},{"nameIdentifier":"50263554","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/search/?qm=50263554"}]},{"creatorNames":[{"creatorName":"イワサキ, ソウタ","creatorNameLang":"ja"},{"creatorName":"イワサキ, ソウタ","creatorNameLang":"ja-Kana"},{"creatorName":"Iwasaki, Sota","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"ベッチャク, ユウタ","creatorNameLang":"ja"},{"creatorName":"ベッチャク, ユウタ","creatorNameLang":"ja-Kana"},{"creatorName":"Becchaku, Yuta","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"ヤベ, シュン","creatorNameLang":"ja"},{"creatorName":"ヤベ, シュン","creatorNameLang":"ja-Kana"},{"creatorName":"Yabe, Shun","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"モリタ, コウタロウ","creatorNameLang":"ja"},{"creatorName":"モリタ, コウタロウ","creatorNameLang":"ja-Kana"},{"creatorName":"Morita, Kotaro","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"水口, 仁志","creatorNameLang":"ja"},{"creatorName":"ミズグチ, ヒトシ","creatorNameLang":"ja-Kana"},{"creatorName":"Mizuguchi, Hitoshi","creatorNameLang":"en"}],"familyNames":[{"familyName":"水口","familyNameLang":"ja"},{"familyName":"ミズグチ","familyNameLang":"ja-Kana"},{"familyName":"Mizuguchi","familyNameLang":"en"}],"givenNames":[{"givenName":"仁志","givenNameLang":"ja"},{"givenName":"ヒトシ","givenNameLang":"ja-Kana"},{"givenName":"Hitoshi","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"807","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"303129/profile-ja.html","nameIdentifierScheme":"徳島大学 教育研究者総覧","nameIdentifierURI":"http://pub2.db.tokushima-u.ac.jp/ERD/person/303129/profile-ja.html"},{"nameIdentifier":"30333991","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/search/?qm=30333991"}]},{"creatorNames":[{"creatorName":"ヒラヤマ, ナオキ","creatorNameLang":"ja"},{"creatorName":"ヒラヤマ, ナオキ","creatorNameLang":"ja-Kana"},{"creatorName":"Hirayama, Naoki","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2020-08-17"}],"displaytype":"detail","filename":"analsci_36_8_941.pdf","filesize":[{"value":"283 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tokushima-u.repo.nii.ac.jp/record/2007194/files/analsci_36_8_941.pdf"},"version_id":"27e38d69-c476-4745-93de-50c2f9a02688"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Carbon nanodot","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"characterization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"capillary electrophoresis","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"micellar electrokinetic chromatography","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"affinity capillary electrophoresis","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Capillary Electrophoretic Characterization of Water-soluble Carbon Nanodots Formed from Glutamic Acid and Boric Acid under Microwave Irradiation","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Capillary Electrophoretic Characterization of Water-soluble Carbon Nanodots Formed from Glutamic Acid and Boric Acid under Microwave Irradiation","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-08-17"},"publish_date":"2020-08-17","publish_status":"0","recid":"2007194","relation_version_is_last":true,"title":["Capillary Electrophoretic Characterization of Water-soluble Carbon Nanodots Formed from Glutamic Acid and Boric Acid under Microwave Irradiation"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2025-01-29T13:58:07.925184+00:00"}