{"created":"2024-10-30T10:05:07.500816+00:00","id":2007942,"links":{},"metadata":{"_buckets":{"deposit":"7c352017-a958-4c68-93b7-de2f2afefdd9"},"_deposit":{"created_by":7,"id":"2007942","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2007942"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02007942","sets":["1713853213384:1713853295607"]},"author_link":["378"],"control_number":"2007942","item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-06-28","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"1618","bibliographicPageStart":"1595","bibliographicVolumeNumber":"14","bibliographic_titles":[{"bibliographic_title":"Beilstein Journal of Organic Chemistry","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"To synthesize nucleoside and oligosaccharide derivatives, we often use a glycosylation reaction to form a glycoside bond. Coupling reactions between a nucleobase and a sugar donor in the former case, and the reaction between an acceptor and a sugar donor of in the latter are carried out in the presence of an appropriate activator. As an activator of the glycosylation, a combination of a Lewis acid catalyst and a hypervalent iodine was developed for synthesizing 4’-thionucleosides, which could be applied for the synthesis of 4’-selenonucleosides as well. The extension of hypervalent iodine-mediated glycosylation allowed us to couple a nucleobase with cyclic allylsilanes and glycal derivatives to yield carbocyclic nucleosides and 2’,3’-unsaturated nucleosides, respectively. In addition, the combination of hypervalent iodine and Lewis acid could be used for the glycosylation of glycals and thioglycosides to produce disaccharides. In this paper, we review the use of hypervalent iodine-mediated glycosylation reactions for the synthesis of nucleosides and oligosaccharide derivatives.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Beilstein-Institut","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"収録物ID","attribute_value_mlt":[{"subitem_source_identifier":"18605397","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1715043197608":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access"}]},"item_1722929371688":{"attribute_name":"出版社版DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"10.3762/bjoc.14.137"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.3762/bjoc.14.137","subitem_relation_type_select":"DOI"}}]},"item_1723180141928":{"attribute_name":"EID","attribute_value_mlt":[{"subitem_identifier_type":"URI","subitem_identifier_uri":"340525"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ヨシムラ, ユウイチ","creatorNameLang":"ja"},{"creatorName":"ヨシムラ, ユウイチ","creatorNameLang":"ja-Kana"},{"creatorName":"Yoshimura, Yuichi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"ワカマツ, ヒデアキ","creatorNameLang":"ja"},{"creatorName":"ワカマツ, ヒデアキ","creatorNameLang":"ja-Kana"},{"creatorName":"Wakamatsu, Hideaki","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"ナトリ, ヨシヒロ","creatorNameLang":"ja"},{"creatorName":"ナトリ, ヨシヒロ","creatorNameLang":"ja-Kana"},{"creatorName":"Natori, Yoshihiro","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"サイトウ, ユカコ","creatorNameLang":"ja"},{"creatorName":"サイトウ, ユカコ","creatorNameLang":"ja-Kana"},{"creatorName":"Saito, Yukako","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"南川, 典昭","creatorNameLang":"ja"},{"creatorName":"ミナカワ, ノリアキ","creatorNameLang":"ja-Kana"},{"creatorName":"Minakawa, Noriaki","creatorNameLang":"en"}],"familyNames":[{"familyName":"南川","familyNameLang":"ja"},{"familyName":"ミナカワ","familyNameLang":"ja-Kana"},{"familyName":"Minakawa","familyNameLang":"en"}],"givenNames":[{"givenName":"典昭","givenNameLang":"ja"},{"givenName":"ノリアキ","givenNameLang":"ja-Kana"},{"givenName":"Noriaki","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"378","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"189780/profile-ja.html","nameIdentifierScheme":"徳島大学 教育研究者総覧","nameIdentifierURI":"http://pub2.db.tokushima-u.ac.jp/ERD/person/189780/profile-ja.html"},{"nameIdentifier":"40209820","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/search/?qm=40209820"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2020-09-02"}],"displaytype":"detail","filename":"bjoc_14_1595.pdf","filesize":[{"value":"1.33 MB"}],"format":"application/pdf","licensetype":"license_0","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tokushima-u.repo.nii.ac.jp/record/2007942/files/bjoc_14_1595.pdf"},"version_id":"ef95704b-13ed-457d-9cd0-83dae0f96f4d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"glycosylation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"hypervalent iodine","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Lewis acid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"nucleoside","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"oligosaccharide","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Glycosylation reactions mediated by hypervalent iodine : application to the synthesis of nucleosides and carbohydrates","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Glycosylation reactions mediated by hypervalent iodine : application to the synthesis of nucleosides and carbohydrates","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-09-02"},"publish_date":"2020-09-02","publish_status":"0","recid":"2007942","relation_version_is_last":true,"title":["Glycosylation reactions mediated by hypervalent iodine : application to the synthesis of nucleosides and carbohydrates"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2025-01-28T00:34:00.555354+00:00"}