{"created":"2024-11-22T07:52:52.887967+00:00","id":2008890,"links":{},"metadata":{"_buckets":{"deposit":"abf9d0ed-d7d2-4635-859f-ca6a86b70d88"},"_deposit":{"created_by":7,"id":"2008890","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2008890"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02008890","sets":["1713853213384:1713853295607"]},"author_link":["53","59"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2005-12-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"546","bibliographicPageStart":"539","bibliographicVolumeNumber":"47","bibliographic_titles":[{"bibliographic_title":"Polymer","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Radical polymerization of N-isopropylacrylamide (NIPAAm) in toluene was investigated in the presence of bidentate Lewis base such as diphosphonates.  Isotacticity of the obtained poly(NIPAAm)s slightly increased at –80°C, whereas syndiotactic-rich poly(NIPAAm)s were obtained at –40 to 0°C.  This result corresponded to the results observed in the presence of primary alkyl phosphates.  NMR analysis revealed that NIPAAm monomer and tetraisopropyl methylenebisphosphonate formed mono-binding hydrogen-bond-assisted complex at 0°C, but a chelate complex at –80°C.  Thus, it was concluded that the stereospecificity in NIPAAm polymerization strongly depended on the complexation mode of the added bidentate Lewis base.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"© 2005. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"収録物ID","attribute_value_mlt":[{"subitem_source_identifier":"00323861","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA11537383","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1715043197608":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access"}]},"item_1722929371688":{"attribute_name":"出版社版DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"10.1016/j.polymer.2005.11.057"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.polymer.2005.11.057","subitem_relation_type_select":"DOI"}}]},"item_1723180141928":{"attribute_name":"EID","attribute_value_mlt":[{"subitem_identifier_type":"URI","subitem_identifier_uri":"130813"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"平野, 朋広","creatorNameLang":"ja"},{"creatorName":"ヒラノ, トモヒロ","creatorNameLang":"ja-Kana"},{"creatorName":"Hirano, Tomohiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"平野","familyNameLang":"ja"},{"familyName":"ヒラノ","familyNameLang":"ja-Kana"},{"familyName":"Hirano","familyNameLang":"en"}],"givenNames":[{"givenName":"朋広","givenNameLang":"ja"},{"givenName":"トモヒロ","givenNameLang":"ja-Kana"},{"givenName":"Tomohiro","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"59","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"10681/profile-ja.html","nameIdentifierScheme":"徳島大学 教育研究者総覧","nameIdentifierURI":"http://pub2.db.tokushima-u.ac.jp/ERD/person/10681/profile-ja.html"},{"nameIdentifier":"80314839","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/search/?qm=80314839"}]},{"creatorNames":[{"creatorName":"キタジマ, ヒロコ","creatorNameLang":"ja"},{"creatorName":"キタジマ, ヒロコ","creatorNameLang":"ja-Kana"},{"creatorName":"Kitajima, Hiroko","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"妹尾, 真紀子","creatorNameLang":"ja"},{"creatorName":"セノオ, マキコ","creatorNameLang":"ja-Kana"},{"creatorName":"Seno, Makiko","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"佐藤, 恒之","creatorNameLang":"ja"},{"creatorName":"サトウ, ツネユキ","creatorNameLang":"ja-Kana"},{"creatorName":"Sato, Tsuneyuki","creatorNameLang":"en"}],"familyNames":[{"familyName":"佐藤","familyNameLang":"ja"},{"familyName":"サトウ","familyNameLang":"ja-Kana"},{"familyName":"Sato","familyNameLang":"en"}],"givenNames":[{"givenName":"恒之","givenNameLang":"ja"},{"givenName":"ツネユキ","givenNameLang":"ja-Kana"},{"givenName":"Tsuneyuki","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"53","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"10673/profile-ja.html","nameIdentifierScheme":"徳島大学 教育研究者総覧","nameIdentifierURI":"http://pub2.db.tokushima-u.ac.jp/ERD/person/10673/profile-ja.html"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2021-05-20"}],"displaytype":"detail","filename":"polymer_47_2_539.pdf","filesize":[{"value":"633 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tokushima-u.repo.nii.ac.jp/record/2008890/files/polymer_47_2_539.pdf"},"version_id":"bcab2566-cf51-4f76-a601-f91d77cdbf76"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Hydrogen bond","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Stereospecific radical polymerization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Chelate complex","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Hydrogen-bond-assisted stereocontrol in the radical polymerization of N-isopropylacrylamide with bidentate Lewis base","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Hydrogen-bond-assisted stereocontrol in the radical polymerization of N-isopropylacrylamide with bidentate Lewis base","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-05-20"},"publish_date":"2021-05-20","publish_status":"0","recid":"2008890","relation_version_is_last":true,"title":["Hydrogen-bond-assisted stereocontrol in the radical polymerization of N-isopropylacrylamide with bidentate Lewis base"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2025-01-24T02:23:45.502421+00:00"}