{"created":"2024-12-12T01:12:42.499156+00:00","id":2009063,"links":{},"metadata":{"_buckets":{"deposit":"27cab3c5-cf5c-4559-bdd5-d1ff20d038d6"},"_deposit":{"created_by":7,"id":"2009063","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2009063"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02009063","sets":["1713853213384:1713853295607"]},"author_link":["371"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-11-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"319","bibliographicPageStart":"316","bibliographicVolumeNumber":"50","bibliographic_titles":[{"bibliographic_title":"Chemistry Letters","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A 14N and 1H NMR spectroscopic study 1 was carried out to shed light on the microscopic aspects of the reaction of model alkylamines at a supercritical temperature of 400 °C. It is disclosed that NH3 and ROH (R = CH3CH2 and CH3 (CH2)3) are initially produced from the hydrolysis of ethylamine and butylamine, respectively. When the water density is doubled from 0.2 g cm−3, the pseudo-first-order reaction rate is markedly enhanced beyond the linear response. It suggests that the transition state of C-N bond cleavage is in a dipolar (ionic) state that can be more stabilized due to the many-body solvation by highly polar water molecules at a higher density.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Chemical Society of Japan","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"© 2021 The Chemical Society of Japan","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"収録物ID","attribute_value_mlt":[{"subitem_source_identifier":"13480715","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"AA12179675","subitem_source_identifier_type":"NCID"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_1715043197608":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access"}]},"item_1722929371688":{"attribute_name":"出版社版DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"10.1246/cl.200783"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1246/cl.200783","subitem_relation_type_select":"DOI"}}]},"item_1723180141928":{"attribute_name":"EID","attribute_value_mlt":[{"subitem_identifier_type":"URI","subitem_identifier_uri":"372533"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"吉田, 健","creatorNameLang":"ja"},{"creatorName":"ヨシダ, ケン","creatorNameLang":"ja-Kana"},{"creatorName":"Yoshida, Ken","creatorNameLang":"en"}],"familyNames":[{"familyName":"吉田","familyNameLang":"ja"},{"familyName":"ヨシダ","familyNameLang":"ja-Kana"},{"familyName":"Yoshida","familyNameLang":"en"}],"givenNames":[{"givenName":"健","givenNameLang":"ja"},{"givenName":"ケン","givenNameLang":"ja-Kana"},{"givenName":"Ken","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"371","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"189117/profile-ja.html","nameIdentifierScheme":"徳島大学 教育研究者総覧","nameIdentifierURI":"http://pub2.db.tokushima-u.ac.jp/ERD/person/189117/profile-ja.html"},{"nameIdentifier":"80549171","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/search/?qm=80549171"}]},{"creatorNames":[{"creatorName":"ヨシオカ, ハルカ","creatorNameLang":"ja"},{"creatorName":"ヨシオカ, ハルカ","creatorNameLang":"ja-Kana"},{"creatorName":"Yoshioka, Haruka","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"ウシグサ, ナツコ","creatorNameLang":"ja"},{"creatorName":"ウシグサ, ナツコ","creatorNameLang":"ja-Kana"},{"creatorName":"Ushigusa, Natsuko","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"ナカハラ, マサル","creatorNameLang":"ja"},{"creatorName":"ナカハラ, マサル","creatorNameLang":"ja-Kana"},{"creatorName":"Nakahara, Masaru","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2021-08-02"}],"displaytype":"detail","filename":"cl_50_2_316.pdf","filesize":[{"value":"916 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tokushima-u.repo.nii.ac.jp/record/2009063/files/cl_50_2_316.pdf"},"version_id":"a4e5faf6-b1a7-4236-9362-6bcbbfa3c5da"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Film forming amines","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Supercritical water","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Nuclear magnetic resonance","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"14N NMR Evidence for Initial Production of NH3 Accompanied by Alcohol from the Hydrolysis of Ethylamine and Butylamine in Supercritical Water","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"14N NMR Evidence for Initial Production of NH3 Accompanied by Alcohol from the Hydrolysis of Ethylamine and Butylamine in Supercritical Water","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-08-02"},"publish_date":"2021-08-02","publish_status":"0","recid":"2009063","relation_version_is_last":true,"title":["14N NMR Evidence for Initial Production of NH3 Accompanied by Alcohol from the Hydrolysis of Ethylamine and Butylamine in Supercritical Water"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2025-01-28T00:29:10.859296+00:00"}