{"created":"2024-12-12T07:22:59.631070+00:00","id":2009866,"links":{},"metadata":{"_buckets":{"deposit":"f493378b-615f-4d18-b380-ae2650fbcd29"},"_deposit":{"created_by":7,"id":"2009866","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2009866"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02009866","sets":["1713853213384:1713853295607"]},"author_link":["824"],"control_number":"2009866","item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-02-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"5153","bibliographicPageStart":"5146","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"ACS Omega","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Daicel Chiralpak IA, IB, and IC, which are the polysaccharide-based chiral stationary phase (CSP) columns for high-performance liquid chromatography (HPLC), were applied in the separation of the non-enantiomeric isomeric mixtures obtained by the various allylation reactions and were highly effective in separating the regio- and (E)/(Z)-isomers in the allylation products. Due to the close structural similarity of the isomeric allylic compounds in the reaction mixtures, separations of the isomers are laborious and could not be accomplished by the conventional methods such as silica gel column chromatography, silica gel HPLC, preparative GPC, distillation, and so forth. This study has shown potential advantages of using the polysaccharide-based CSP columns in the separation of not only enantiomeric but also non-enantiomeric isomeric mixtures.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"収録物ID","attribute_value_mlt":[{"subitem_source_identifier":"24701343","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1715043197608":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access"}]},"item_1722929371688":{"attribute_name":"出版社版DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"10.1021/acsomega.1c06187"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acsomega.1c06187","subitem_relation_type_select":"DOI"}}]},"item_1723180141928":{"attribute_name":"EID","attribute_value_mlt":[{"subitem_identifier_type":"URI","subitem_identifier_uri":"384345"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"オオジ, タケヒト","creatorNameLang":"ja"},{"creatorName":"オオジ, タケヒト","creatorNameLang":"ja-Kana"},{"creatorName":"Ohji, Takehito","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"オオニシ, アツシ","creatorNameLang":"ja"},{"creatorName":"オオニシ, アツシ","creatorNameLang":"ja-Kana"},{"creatorName":"Ohnishi, Atsushi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"小笠原, 正道","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"824","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2022-05-31"}],"displaytype":"detail","filename":"acsomega_7_6_5146.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_5","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://tokushima-u.repo.nii.ac.jp/record/2009866/files/acsomega_7_6_5146.pdf"},"version_id":"9c383c34-7fc6-41b3-8699-881876475449"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Application of Polysaccharide-Based Chiral High-Performance Liquid Chromatography Columns for the Separation of Regio-, E/Z-, and Enantio–Isomeric Mixtures of Allylic Compounds","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Application of Polysaccharide-Based Chiral High-Performance Liquid Chromatography Columns for the Separation of Regio-, E/Z-, and Enantio–Isomeric Mixtures of Allylic Compounds","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2022-05-31"},"publish_date":"2022-05-31","publish_status":"0","recid":"2009866","relation_version_is_last":true,"title":["Application of Polysaccharide-Based Chiral High-Performance Liquid Chromatography Columns for the Separation of Regio-, E/Z-, and Enantio–Isomeric Mixtures of Allylic Compounds"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2024-12-20T00:03:20.971916+00:00"}