{"created":"2024-12-12T07:36:42.694068+00:00","id":2010032,"links":{},"metadata":{"_buckets":{"deposit":"3716d23f-e444-4e5e-90f9-1a5d61f6797f"},"_deposit":{"created_by":7,"id":"2010032","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2010032"},"status":"published"},"_oai":{"id":"oai:tokushima-u.repo.nii.ac.jp:02010032","sets":["1713853213384:1713853295607"]},"author_link":["355"],"control_number":"2010032","item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-01-28","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"3782","bibliographicPageStart":"3774","bibliographicVolumeNumber":"12","bibliographic_titles":[{"bibliographic_title":"RSC Advances","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Hydrothermally synthesized poorly-crystalline metastable Zr–W binary hydroxide (W/Zr = 2), after calcination, was confirmed to be a strong solid acid catalyst to promote the alkylation of anisole with benzyl alcohol. The preparation conditions, structure of the as-prepared catalysts and the calcined hydroxides were investigated using XRD, nitrogen adsorption isotherms, TG-DTA, and XANES/EXAFS techniques. The crystalline phase was controlled by the hydrochloric acid concentration used for preparing a mother gel, and 5–9 M HCl was suitable for preparing the active phase. The tungsten species exists as a six-valent WO6 distorted octahedron connected with the ZrO7 unit via corner-sharing linkages. The incompleteness of the network structure is suggested to be responsible for the solid acidity.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Royal Society of Chemistry","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"収録物ID","attribute_value_mlt":[{"subitem_source_identifier":"20462069","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1715043197608":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open 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alcohol","subitem_title_language":"en"}]},"item_type_id":"40001","owner":"7","path":["1713853295607"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2022-06-28"},"publish_date":"2022-06-28","publish_status":"0","recid":"2010032","relation_version_is_last":true,"title":["Hydrothermally synthesized poorly-crystalline binary oxides with ZrW2O8 composition : preparation, structural analysis, and catalytic activity for the alkylation of anisole with benzyl alcohol"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2025-01-28T00:11:02.115332+00:00"}