| アイテムタイプ |
文献 / Documents(1) |
| 公開日 |
2016-08-22 |
| アクセス権 |
|
|
アクセス権 |
open access |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版社版DOI |
|
|
|
関連識別子 |
https://www.jstage.jst.go.jp/article/jcej/49/2/49_15we106/_article |
|
|
関連名称 |
10.1252/jcej.15we106 |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| タイトル |
|
|
タイトル |
Oxidative Dehydrogenation of Isobutane to Isobutene on Metal-doped MCM-41 Catalysts |
| 著者 |
エヒロ, タクヤ
イタガキ, アイ
ミス, ヒサノブ
倉科, 昌
中川, 敬三
WEKO
250
e-Rad_Researcher
60423555
| ja |
中川, 敬三
中川, 敬三
ISNI
|
| ja-Kana |
ナカガワ, ケイゾウ
ナカガワ, ケイゾウ
|
| en |
Nakagawa, Keizo
Nakagawa, Keizo
|
Search repository
加藤, 雅裕
カトウ, ユウキ
ニノミヤ, ワタル
杉山, 茂
|
| 抄録 |
|
|
内容記述 |
MCM-41 (#41 Mobil Composition of Matter) is a favorable material for heterogeneous reactions because of its unique porous structure. However, the catalytic activity of MCM-41 for the oxidative dehydrogenation (ODH) of isobutane to isobutene is known to be quite low. In the present study, a metal-doping method was employed to improve this catalytic activity. Doping of Cr, Co, Ni, or Mo into MCM-41 resulted in a great improvement in the catalytic activity. Since chromium-doped MCM-41 (Cr-MCM-41) showed the greatest catalytic activity among these catalysts, its redox property was further analyzed via XPS, XAFS and H2-TPR techniques. The XPS spectrum of Cr-MCM-41 suggested that it has Cr3+ and Cr6+ species on its surface. Also, a pre-edge peak due to Cr6+ species was confirmed in the XANES spectrum of Cr-MCM-41. In H2-TPR measurement, Cr-MCM-41 was more reducible than crystalline Cr2O3, which showed low catalytic activity for the ODH of isobutane. The reducible Cr6+ species on Cr-MCM-41 contributed to an improvement in the catalytic activity of MCM-41. |
| キーワード |
|
|
主題 |
Oxidative Dehydrogenation |
| キーワード |
|
|
主題 |
Isobutane |
| キーワード |
|
|
主題 |
Isobutene |
| キーワード |
|
|
主題 |
MCM-41 |
| キーワード |
|
|
主題 |
Metal-Doping |
| 書誌情報 |
en : Journal of Chemical Engineering of Japan
巻 49,
号 2,
p. 136-143,
発行日 2016
|
| 収録物ID |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
00219592 |
| 収録物ID |
|
|
収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA00709658 |
| 権利情報 |
|
|
権利情報 |
Copyright © 2016 The Society of Chemical Engineers, Japan |
| EID |
|
|
識別子 |
297334 |
| 言語 |
|
|
言語 |
eng |
LID201608222006.pdf (1.59 MB)
