| アイテムタイプ |
文献 / Documents(1) |
| 公開日 |
2016-10-31 |
| アクセス権 |
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アクセス権 |
open access |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 出版社版DOI |
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関連識別子 |
https://www.jstage.jst.go.jp/article/jcej/46/9/46_13we059/_article |
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関連名称 |
10.1252/jcej.13we059 |
| 出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| タイトル |
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タイトル |
The Catalytic Conversion of 1,2-Propandiol to Propanal on FSM-16 Molded by Wet-Treatment and Pressurization |
| 著者 |
杉山, 茂
オカダ, ヤスヒロ
コサカ, ヨウヘイ
中川, 敬三
WEKO
250
e-Rad_Researcher
60423555
| ja |
中川, 敬三
中川, 敬三
ISNI
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| ja-Kana |
ナカガワ, ケイゾウ
ナカガワ, ケイゾウ
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| en |
Nakagawa, Keizo
Nakagawa, Keizo
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Search repository
加藤, 雅裕
カトウ, ユウキ
アキハラ, シュウジ
ヤスカワ, トシヤ
ニノミヤ, ワタル
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| 抄録 |
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内容記述 |
The catalytic conversion of 1,2-propandiol to propanal is examined using FSM-16 particles (0.85－1.70 mm) molded by wet-treatment and pressurization. When FSM-16 was molded with 0.6 g of pressurization and supplied to the catalytic conversion of 1,2-propandiol at 673 K, this system resulted in a 94.8% conversion of 1,2-propandiol and 90.5% selectivity to propanal at 0.25 h on-stream, which was the maximum amount of activity. However, at 4.50 h on-stream, the activity decreased extremely to deactivation 19.9% conversion of 1,2-propandiol and 84.7% selectivity to propanal. In contrast, when FSM-16 molded with wet-treatment (0.15 g) was used for the conversion at 573 K, activity was greatly increased and stable 98.6% conversion of 1,2-propandiol and 56.2% selectivity to propanal at 0.25 h on-stream followed by 91.9% and 52.5%, respectively, at 4.50 h on-stream. The hexagonal structure of FSM-16 was suggested to have contributed to the suitable conversion of 1,2-propandiol to propanal. |
| キーワード |
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主題 |
Catalytic Conversion |
| キーワード |
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主題 |
1,2-Propandiol |
| キーワード |
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主題 |
Propanal |
| キーワード |
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主題 |
FSM-16 |
| 書誌情報 |
en : Journal of Chemical Engineering of Japan
巻 46,
号 9,
p. 620-624,
発行日 2013
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| 収録物ID |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
00219592 |
| 収録物ID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA00709658 |
| 権利情報 |
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権利情報 |
Copyright © 2013 The Society of Chemical Engineers, Japan |
| EID |
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識別子 |
263305 |
| 言語 |
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言語 |
eng |
LID201610312003.pdf (296 KB)
