Item type |
文献 / Documents(1) |
公開日 |
2021-08-26 |
アクセス権 |
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アクセス権 |
open access |
資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
出版社版DOI |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.3390/s150305982 |
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言語 |
ja |
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関連名称 |
10.3390/s150305982 |
出版タイプ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
タイトル |
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タイトル |
Comparison of the Detection Characteristics of Trace Species Using Laser-Induced Breakdown Spectroscopy and Laser Breakdown Time-of-Flight Mass Spectrometry |
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言語 |
en |
著者 |
Wang, Zhenzhen
出口, 祥啓
Yan, Junjie
Liu, Jiping
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抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
The rapid and precise element measurement of trace species, such as mercury, iodine, strontium, cesium, etc. is imperative for various applications, especially for industrial needs. The elements mercury and iodine were measured by two detection methods for comparison of the corresponding detection features. A laser beam was focused to induce plasma. Emission and ion signals were detected using laser-induced breakdown spectroscopy (LIBS) and laser breakdown time-of-flight mass spectrometry (LB-TOFMS). Multi-photon ionization and electron impact ionization in the plasma generation process can be controlled by the pressure and pulse width. The effect of electron impact ionization on continuum emission, coexisting molecular and atomic emissions became weakened in low pressure condition. When the pressure was less than 1 Pa, the plasma was induced by laser dissociation and multi-photon ionization in LB-TOFMS. According to the experimental results, the detection limits of mercury and iodine in N2 were 3.5 ppb and 60 ppb using low pressure LIBS. The mercury and iodine detection limits using LB-TOFMS were 1.2 ppb and 9.0 ppb, which were enhanced due to different detection features. The detection systems of LIBS and LB-TOFMS can be selected depending on the condition of each application. |
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言語 |
en |
キーワード |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
laser-induced breakdown spectroscopy (LIBS) |
キーワード |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
laser breakdown time-of-flight mass spectrometry (LB-TOFMS) |
キーワード |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
low pressure |
キーワード |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
electron impact ionization |
書誌情報 |
en : Sensors
巻 15,
号 3,
p. 5982-6008,
発行日 2015-03-11
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収録物ID |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
14248220 |
出版者 |
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出版者 |
MDPI |
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言語 |
en |
権利情報 |
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言語 |
en |
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権利情報 |
This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/). |
EID |
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識別子 |
291883 |
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識別子タイプ |
URI |
言語 |
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言語 |
eng |