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Estimating Effective Steric and Electronic Impacts of a Ferrocenyl Group in Organophosphines
https://tokushima-u.repo.nii.ac.jp/records/2009185
https://tokushima-u.repo.nii.ac.jp/records/20091855d0c2829-2521-446f-8a69-40b8aa7f8cad
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
acsomega_6_8_5981.pdf (1.72 MB)
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| Item type | 文献 / Documents(1) | |||||||||||||||||||||||||
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| 公開日 | 2021-09-08 | |||||||||||||||||||||||||
| アクセス権 | ||||||||||||||||||||||||||
| アクセス権 | open access | |||||||||||||||||||||||||
| 資源タイプ | ||||||||||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||||||||||
| 出版社版DOI | ||||||||||||||||||||||||||
| 関連識別子 | https://doi.org/10.1021/acsomega.1c00307 | |||||||||||||||||||||||||
| 関連名称 | 10.1021/acsomega.1c00307 | |||||||||||||||||||||||||
| 出版タイプ | ||||||||||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||||||||||
| タイトル | ||||||||||||||||||||||||||
| タイトル | Estimating Effective Steric and Electronic Impacts of a Ferrocenyl Group in Organophosphines | |||||||||||||||||||||||||
| 著者 |
Hu, Hao
× Hu, Hao
× イチリュウ, ヒロキ
× ナカジマ, キヨヒコ
× 小笠原, 正道
WEKO
824
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| 内容記述 | A series of monodentate ferrocenylphosphines, Fc3P (1a), Fc2PhP (1b), and Fc2ArP (1c; Fc = ferrocenyl, Ar = 3,4-methylenedioxyphenyl), were prepared, and their electronic and steric properties were quantitatively determined. By the IR measurements of their respective Ni(CO)3(phosphine) complexes, the electronic properties of the ferrocenyl group in organophosphines were estimated to be similar to those of primary alkyl groups. The ferrocenyl group is a better electron donor than a methyl group and a poorer donor than an ethyl group. The gold(I) chloride complexes of 1a–c were prepared and their X-ray crystal structures were determined. The %Vbur parameters for 1a–c were calculated using the X-ray structural data, and their ″Tolman cone angles″ were estimated. The steric influence of the ferrocenyl group in organophosphines was clarified to be larger than those of cyclohexyl, tert-butyl, and o-tolyl groups and is comparable to that of a mesityl group. | |||||||||||||||||||||||||
| 書誌情報 |
en : ACS Omega 巻 6, 号 8, p. 5981-5989, 発行日 2021-02-14 |
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| 収録物識別子タイプ | ISSN | |||||||||||||||||||||||||
| 収録物識別子 | 24701343 | |||||||||||||||||||||||||
| 出版者 | ||||||||||||||||||||||||||
| 出版者 | ACS Publications | |||||||||||||||||||||||||
| 権利情報 | ||||||||||||||||||||||||||
| 権利情報 | This is an open access article under the CC BY-NC-ND license. | |||||||||||||||||||||||||
| EID | ||||||||||||||||||||||||||
| 識別子 | 374098 | |||||||||||||||||||||||||
| 言語 | ||||||||||||||||||||||||||
| 言語 | eng | |||||||||||||||||||||||||
