Item type |
文献 / Documents(1) |
公開日 |
2022-05-30 |
アクセス権 |
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アクセス権 |
open access |
資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
出版社版DOI |
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関連識別子 |
https://doi.org/10.2355/isijinternational.ISIJINT-2021-406 |
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関連名称 |
10.2355/isijinternational.ISIJINT-2021-406 |
出版タイプ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
タイトル |
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タイトル |
Analysis of Leachate Copper from Sediment at a Small Abandoned Mine Site by Handy-type Liquid Electrode Plasma Atomic Emission Spectrometer |
著者 |
山本, 孝
ヤマシタ, アユミ
ヨコヤマ, ノゾミ
ユクモト, アキラ
今井, 昭二
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抄録 |
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内容記述 |
Sediment, soil and drainage water were collected at an abandoned copper mine, and the leachate copper prepared with 1M HCl were qualitatively analyzed by a handy elemental analyzer based on liquid electrode plasma atomic emission spectrometry (LEP-AES). Quantitative values obtained by the handy analyzer with standard addition or conventional calibration method combining with self-internal standard method, and ones by flame atomic absorption spectrometer were compared. The analytical condition for LEP-AES, the accuracy and the precision were discussed. The elongation of interval of pulsed applied voltage enhanced intensities of emission line, but background rising for copper emission line overlapping tail of broad OH band prevent expected improvement of the limit of detection. Copper species in sediment exist as divalent basic copper sulfate confirmed by XANES/EXAFS spectra recorded by a laboratory type spectrometer. |
キーワード |
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主題 |
handy atomic emission spectrometer |
キーワード |
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主題 |
abandoned copper mine |
キーワード |
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主題 |
acid leachate |
キーワード |
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主題 |
liquid electrode plasma |
キーワード |
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主題 |
laboratory XAFS spectrometer |
キーワード |
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主題 |
basic copper sulfate |
書誌情報 |
en : ISIJ International
巻 62,
号 5,
p. 854-859,
発行日 2022-05-15
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収録物ID |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
09151559 |
収録物ID |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
13475460 |
収録物ID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA10680712 |
出版者 |
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出版者 |
The Iron and Steel Institute of Japan |
権利情報 |
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権利情報 |
© 2022 The Iron and Steel Institute of Japan. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs license (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
EID |
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識別子 |
382421 |
言語 |
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言語 |
eng |