| アイテムタイプ |
文献 / Documents(1) |
| 公開日 |
2022-08-10 |
| アクセス権 |
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アクセス権 |
open access |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 出版社版DOI |
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関連識別子 |
https://doi.org/10.1021/acs.orglett.2c01215 |
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関連名称 |
10.1021/acs.orglett.2c01215 |
| 出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| タイトル |
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タイトル |
Total Syntheses of Proposed Structures of 4,10-Dihydroxy-8,12-guaianolides |
| 著者 |
キムラ, ユキ
オオハシ, エイサク
カランジット, サンギータ
タニグチ, タカシ
中山, 淳
イマガワ, ヒロシ
佐藤, 亮太
難波, 康祐
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| 抄録 |
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内容記述 |
The first total syntheses of two 4,10-dihydroxy 8,12-guaianolides that were reported to be natural products, were achieved. Toward the syntheses of a collection of related guaianolides, the typical 5,7-fused system of 8,12-guaianolides was constructed by a ring expansion reaction of a hydroxylated coronafacic acid analog that can be practically synthesized and optically resolved. The total syntheses of these compounds revealed that the previously reported structures of both natural products were incorrect. |
| 書誌情報 |
en : Organic Letters
巻 24,
号 17,
p. 3297-3301,
発行日 2022-04-21
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| 収録物ID |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
15237060 |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
15237052 |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA11347843 |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA1218968X |
| 出版者 |
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出版者 |
ACS Publications |
| 権利情報 |
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権利情報 |
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.2c01215. |
| EID |
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識別子 |
388689 |
| 言語 |
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言語 |
eng |
orglett_24_17_3297.pdf (634 KB)
