| Item type |
文献 / Documents(1) |
| 公開日 |
2024-01-11 |
| アクセス権 |
|
|
アクセス権 |
open access |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版社版DOI |
|
|
|
関連識別子 |
https://doi.org/10.1002/chem.202300858 |
|
|
関連名称 |
10.1002/chem.202300858 |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| タイトル |
|
|
タイトル |
Remote Electronic Effect of Chiral N-Heterocyclic Carbene Catalyst on an Asymmetric Benzoin Reaction |
| 著者 |
猪熊, 翼
ハシモト, ケンタロウ
フジワラ, タツヤ
Sun, Chunzhao
クワノ, サトル
山田, 健一
|
| 抄録 |
|
|
内容記述 |
A remote electronic effect of chiral aminoindanol-derived N-heterocyclic carbene catalyst on an asymmetric benzoin reaction was investigated. The catalyst bearing remote electron-withdrawing substituents increased enantioselectivity of the reaction at the cost of the reaction rate. DFT calculations rationalized the increased enantioselectivity. |
| キーワード |
|
|
主題 |
asymmetric reaction |
| キーワード |
|
|
主題 |
benzoin reaction |
| キーワード |
|
|
主題 |
density functional theory calculation |
| キーワード |
|
|
主題 |
N-heterocyclic carbene |
| キーワード |
|
|
主題 |
organocatalysis |
| 書誌情報 |
en : Chemistry- A European Journal
巻 29,
号 38,
p. e202300858,
発行日 2023-04-17
|
| 収録物ID |
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
15213765 |
| 収録物ID |
|
|
収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA11076269 |
| 出版者 |
|
|
出版者 |
Wiley-VCH |
| 権利情報 |
|
|
権利情報 |
This is the peer reviewed version of the following article: Inokuma, Tsubasa, Hashimoto, Kentaro, Fujiwara, Tatsuya, Sun, Chunzhao, Kuwano, Satoru, Yamada, Ken-ichi, Chem. Eur. J. 2023, 29, 38, e202300858., which has been published in final form at https://doi.org/10.1002/chem.202300858. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. |
| EID |
|
|
識別子 |
395405 |
| 言語 |
|
|
言語 |
eng |
chemej_29_38_e202300858.pdf (1.43 MB)
