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Application of Polysaccharide-Based Chiral High-Performance Liquid Chromatography Columns for the Separation of Regio-, E/Z-, and Enantio–Isomeric Mixtures of Allylic Compounds
https://tokushima-u.repo.nii.ac.jp/records/2009866
https://tokushima-u.repo.nii.ac.jp/records/200986642873737-259e-40de-aeea-a9177a2c0327
| 名前 / ファイル | ライセンス | アクション |
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acsomega_7_6_5146.pdf (1.3 MB)
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| Item type | 文献 / Documents(1) | |||||||||||||||||
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| 公開日 | 2022-05-31 | |||||||||||||||||
| アクセス権 | ||||||||||||||||||
| アクセス権 | open access | |||||||||||||||||
| 資源タイプ | ||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||
| 出版社版DOI | ||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||
| 関連識別子 | https://doi.org/10.1021/acsomega.1c06187 | |||||||||||||||||
| 言語 | ja | |||||||||||||||||
| 関連名称 | 10.1021/acsomega.1c06187 | |||||||||||||||||
| 出版タイプ | ||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||
| タイトル | ||||||||||||||||||
| タイトル | Application of Polysaccharide-Based Chiral High-Performance Liquid Chromatography Columns for the Separation of Regio-, E/Z-, and Enantio–Isomeric Mixtures of Allylic Compounds | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 著者 |
オオジ, タケヒト
× オオジ, タケヒト
× オオニシ, アツシ
× 小笠原, 正道 |
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| 抄録 | ||||||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||||||
| 内容記述 | Daicel Chiralpak IA, IB, and IC, which are the polysaccharide-based chiral stationary phase (CSP) columns for high-performance liquid chromatography (HPLC), were applied in the separation of the non-enantiomeric isomeric mixtures obtained by the various allylation reactions and were highly effective in separating the regio- and (E)/(Z)-isomers in the allylation products. Due to the close structural similarity of the isomeric allylic compounds in the reaction mixtures, separations of the isomers are laborious and could not be accomplished by the conventional methods such as silica gel column chromatography, silica gel HPLC, preparative GPC, distillation, and so forth. This study has shown potential advantages of using the polysaccharide-based CSP columns in the separation of not only enantiomeric but also non-enantiomeric isomeric mixtures. | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 書誌情報 |
en : ACS Omega 巻 7, 号 6, p. 5146-5153, 発行日 2022-02-03 |
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| 収録物ID | ||||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||||
| 収録物識別子 | 24701343 | |||||||||||||||||
| 出版者 | ||||||||||||||||||
| 出版者 | ACS Publications | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 権利情報 | ||||||||||||||||||
| 言語 | en | |||||||||||||||||
| 権利情報 | This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). | |||||||||||||||||
| EID | ||||||||||||||||||
| 識別子 | 384345 | |||||||||||||||||
| 識別子タイプ | URI | |||||||||||||||||
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| 言語 | eng | |||||||||||||||||
